Synthesis and characterization of new metallophthalocyanines containing O_4S_2 mixed-donor substituted macrocyclic groups

Authors: MELTEM BETÜL KILIÇASLAN, HALİT KANTEKİN

Abstract: New phthalocyanine compounds containing mixed-donor substituted macrocyclic groups were synthesized. The complexes of metal phthalocyanines 3--5 were prepared by the reaction of 2 to get dinitrile derivative complexes by means of the corresponding anhydrous metal salts. Structures of the new compounds were characterized by IR, ^1H NMR, ^{13}C NMR, elemental analysis, and MS spectral data.

Keywords: Phthalonitrile, cyclotetramerization, dicarbonitrile, phthalocyanine

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