Preparation, characterization, and binding profile of imprinted semi-IPN cryogel composite for aluminum

Authors: SHAHNILA SHAH, HUMA SHAIKH, NAJMA MEMON, MUHAMMAD IGBAL BHANGER, TAHIRA QURESHI, HUMAIRA KHAN, ADİL DENİZLİ

Abstract: Human body is greatly exposed to aluminum due to its high abundance in the environment. This nonessential metal is a threat to the patients of chronic renal disorders, as it is easily retained in their plasma and quickly accumulates in different tissues. Thus, there is great need to remove it from the aqueous environment. In this study, Al$^{3+}$ imprinted semiinterpenetrating polymer network (semi-IPN)-based cryogel composite was prepared and applied for the purification of environmental and drinking water samples from aluminum. Poly (2-hydroxyethyl methacrylate) (pHEMA) discs were produced via cryogenic treatment and imprinted semi-IPN was introduced to the 3-(trimethoxysilyl) propyl acrylate-modified macroporous cryogel discs. The adsorption properties and selectivity of the aluminum (III) imprinted semi-IPN cryogel composite were studied in detail. The imprinted semi-IPN cryogel composite showed good selectivity towards aluminum (III)$^{\, }$ions with the imprinting factor (IF) of 76.4 in the presence of competing copper (II), nickle (II),$^{\mathbf{\, }}$and iron (III) ions. The maximum adsorption capacity of 271 $\mu $mol g$^{-1}$ was obtained for aluminum (III) at pH 7.0 within 10 min using imprinted semi-IPN cryogel composite. The good selectivity and reusability of aluminum (III)-imprinted semi-IPN cryogel composite makes this material an eligible candidate for the purification of drinking water from aluminum (III) leaving important minerals remained in the water.

Keywords: Semiinterpenetrating polymeric networks, imprinted polymer, cryogel, composites, aluminum, water purification

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