Crystal Structure of the cis-bis[4-chloro-N-(pyrrolidine-1-carbothioyl)-benzamido] copper(II) Complex

Authors: NEVZAT KÜLCÜ, ULRICH FLÖRKE, HAKAN ARSLAN

Abstract: The crystal and molecular structure of the cis-bis[4-chloro-N-(pyrrolidine-1-carbothioyl)-benzamido] copper(II) complex was determined by single-crystal X-ray diffraction. The title compound, C_{24}H_{24}N_4O_2 S_2Cl_2Cu, crystalizes in the triclinic space group P-1, with Z = 4 and unit cell parameters a = 8.3877(5) Å, b = 12.7904(8) Å, c = 24.160(2) Å, \alpha = 95.923(1) °, \beta = 96.001(1) °, and \gamma = 95.048(1) °. The copper atom is 4-fold coordinated by 2 S and 2 O atoms and shows a slightly distorted planar quadratic ligand arrangement.

Keywords: Thioureas, X-ray structures, Benzoylthiourea complexes, Cu(II) complex

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