The Facile Synthesis of Cyclopentanoid Antibiotic Kjellmanianone

Authors: Ayhan S. DEMİR, Cihangir TANYELİ, Volkan GÜLBEYAZ, Hülya AKGÜL

Abstract: The synthesis of cyclopentanoid antibiotic Kjellmanianone is described in this study. The C-acylation of lithium enolates of 3-Methoxycyclopentenone by N-carbomethoxyimidazole or methylcyanoformate \beta-ketoester, which when oxidized with Mn(III) acetate produces kjellmanianone in good yield.

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