Bromination of Tetrachlorobenzobarrelene: Polyhalogenated Benzobicyclics

Authors: MEHMET EMİN ŞENGÜL, DEMET DEMİRCİ GÜLTEKİN, SELÇUK EŞSİZ, ARİF DAŞTAN

Abstract: The low and high temperature bromination reaction of tetrachlorobenzobarrelene was studied and the possible role of a neighboring group in rearrangements was investigated. New polyhalogenated benzobicyclic compounds were synthesized. All compounds were characterized properly using NMR spectroscopy.

Keywords: Benzobarrelene, bromination, Wagner-Meerwein rearrangement, polyhalogenides

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