Crystal Structure of cis-bis(N,N-dimethyl-N'-benzoylthioureato)palladium(II)

Authors: GÖKTÜRK AVŞAR, HAKAN ARSLAN, HANS-JURGEN HAUPT, NEVZAT KÜLCÜ

Abstract: In this study cis-bis(N,N-dimethyl-N'-benzoylthioureato) palladium(II) is synthesised and the crystal structure is determined by X-ray diffraction methods. It crystallises in the space group P2_{1}/c, with a = 11.943(1) Å, b = 11.713(1) Å, c = 15.345(1) Å, \beta = 93.90(1)°, and D_{calc} = 1.616 g cm^{-1} for Z = 4. The Pd(II) atom is in a four-coordinate geometry consisting of two thiocarbonyl S and two carbonyl O atoms from two ligand groups. The Pd-S and Pd-O bond lengths are 2.2313(6) and 2.0211(16) Å, respectively.

Keywords: Complex, X-ray structure, single crystal, N,N-dimethyl-N'- benzoylthiourea

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