An expedient synthesis of 6-vinylfulvene

Authors: İHSAN ERDEN, JENNY SABOL, ANA GUBELADZE, ANDREA RUIZ

Abstract: 6-Vinylfulvenes constitute a class of fulvenes that are difficult to access due to the lack of a general method for their synthesis. In particular, the unsubstituted parent system has been very difficult to obtain by existing methods. In this communication we describe a convenient 3-step protocol for the synthesis of the title compound by way of sulfide oxidation and subsequent sulfoxide elimination.

Keywords: Fulvene, vinylfulvene, sulfide, sulfoxide, desulfinylation

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